Girone a
| Pos | Club | P | W | D | L | F | A | GD | Pts |
|---|---|---|---|---|---|---|---|---|---|
| 1 |  SSC Napoli | 10 | 7 | 1 | 2 | 26 | 8 | 18 | 22 |
| 2 |  Liverpool FC | 6 | 5 | 0 | 1 | 17 | 6 | 11 | 15 |
| 3 |  Ajax FC | 6 | 2 | 0 | 4 | 11 | 16 | -5 | 6 |
| 4 |  Rangers FC | 6 | 0 | 0 | 6 | 2 | 22 | -20 | 0 |
 1 - 1Champions League 2022-23 Stadio Diego A. Maradona SSC Napoli vs AC Milan |
1 - 0Champions League 2022-23 Stadio Giuseppe Meazza AC Milan vs SSC Napoli |
 3 - 0Champions League 2022-23 Stadio Diego A. Maradona SSC Napoli vs Eintracht Frankfurt |
0 - 2Champions League 2022-23 Deutsche Bank Park Eintracht Frankfurt vs SSC Napoli |
2 - 0Champions League 2022-23 Anfield Road Stadium Liverpool FC vs SSC Napoli |
3 - 0Champions League 2022-23 Stadio Diego A. Maradona SSC Napoli vs Rangers FC |
